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Krogmann's salt (Read 1680 times)
Gerrit-Jan Linker
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Krogmann's salt
02.02.13 at 12:24:08
 
Krogmann's salt
 
Krogmann's salt is a mixed-valence square planar coordination complex of platinum and cyanide bonded through linear platinum metal chains, sometimes described as molecular wires.
 
Krogmann’s salt is a series of partially oxidized tetracyanoplatinate complexes linked by the platinum-platinum bonds on the top and bottom faces of the planar [Pt(CN)4]n- anions. This salt forms infinite stacks in the solid state based on the overlap of the dz2 orbitals.
 
Source:
http://en.wikipedia.org/wiki/Krogmann%27s_salt
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Gerrit-Jan Linker
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