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Condon Approximation (Read 6261 times)
Gerrit-Jan Linker
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Condon Approximation
09.07.12 at 16:30:04
Condon Approximation
Condon Approximation:
The electronic transition occurs on a time scale short compared to nuclear motion so that the transition probability can be calculated at a fixed nuclear position.
The Condon approximation is a more restricxtive approximation than the BO approximation (nuclear and electronic motions can be separated) in that the Condon approximation demands that the nuclear coordinate be a fixed value.
See also:
Franck Condon Principle
Born Opperheimer Approximation
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« Last Edit: 09.07.12 at 16:34:13 by Gerrit-Jan Linker »  

Gerrit-Jan Linker
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